Recycling of Aluminium–Polymer Composite Packaging Waste Using Green Solvent-Based Delamination
DOI:
https://doi.org/10.52340/atsu.2026.1.27.15Keywords:
aluminium–polymer composite packaging, green solvents, delamination, multilayer waste, circular economy, GeorgiaAbstract
Aluminium–polymer composite packaging waste is among the most difficult packaging streams to recycle because its multilayer structure limits the effectiveness of conventional mechanical processing and often results in landfilling or energy recovery rather than material recovery. This review examines green solvent-based delamination as a sustainable pathway for separating aluminium and polymer fractions from composite packaging waste. The paper discusses the structure of aluminium–polymer laminates, the limitations of conventional recycling, the principles of solvent-based separation, and the performance of major green solvent systems, including ethyl lactate, methyl soyate, gamma-valerolactone, ionic liquids, and deep eutectic solvents. Particular attention is given to the environmental significance of these approaches within the framework of circular economy principles and to their potential relevance for Georgia, where multilayer packaging waste remains insufficiently addressed in current waste management practices. The review demonstrates that green solvent-based delamination offers strong potential for high-purity aluminium recovery and improved valorization of polymer fractions; however, further optimization, scale-up studies, and policy support are required for practical implementation.
Downloads
References
Adam, F., et al. 2025. Recycling of multilayer polymeric barrier films: An overview of recent pioneering works and main challenges.
Ciawi, E., et al. 2025. Multilayer packaging recycling: Challenges, current practices, and future prospects.
EU4Georgia. 2024–2028. Circular cities and regions in Georgia: Building local capacities to advance waste prevention and circular economy.
Georgiopoulou, I., et al. 2021. „Recycling of post-consumer multilayer Tetra Pak® packaging with the selective dissolution-precipitation process.“ Resources, Conservation and Recycling. https://doi.org/10.1016/j.resconrec.2020.105268
GIZ. 2024. Circular economy in Georgia: Opportunities for reusable packaging systems and women’s participation.
Golkaram, M., et al. 2025. „Advancing circularity in multilayer film recycling: Balancing quality and sustainability.“ Polymers. https://doi.org/10.3390/polym17212868
Jasiński, D., et al. 2025. „Sustainability assessment of employing chemical recycling technologies on multilayer packaging waste.“ Sustainability, 17(2), 556. https://doi.org/10.3390/su17020556
Kaiser, K., et al. 2017. „Recycling of polymer-based multilayer packaging: A review.“ Recycling. https://doi.org/10.3390/recycling3010001
Kremser, K., et al. 2022. „Bioleaching/enzyme-based recycling of aluminium and polyethylene from beverage cartons packaging waste.“ Resources, Conservation and Recycling. https://doi.org/10.1016/j.resconrec.2022.106444
Loukodimou, E., et al. 2024a. „Delamination and evaluation of multilayer PE/Al/PET packaging waste separated using a hydrophobic deep eutectic solvent.“ Polymers, 16(19), 2718. https://doi.org/10.3390/polym16192718
Loukodimou, E., et al. 2024b. „Formulation and characterization of deep eutectic solvents and potential application in recycling packaging laminates.“ Polymers, 16(19), 2781. https://doi.org/10.3390/polym16192781
Miękoś, E., et al. 2023. „Separation technology of components of waste pharmaceutical blisters.“ Ecological Chemistry and Engineering S. https://doi.org/10.2478/eces-2023-0034
Mumladze, T., et al. 2019–2020. Research on aluminium-polymer composite packaging recycling in Georgia. Kaunas University of Technology.
Nieminen, H., et al. 2020. „Green solvents in recovery of aluminium and plastic from waste pharmaceutical blister packaging.“ Waste Management. https://doi.org/10.1016/J.WASMAN.2020.03.014
Rosato, A., et al. 2020. New strategy for multilayers packaging recycling. https://doi.org/10.5281/zenodo.4247372
Samorì, C., et al. 2023. „Recycling of multilayer packaging waste with sustainable solvents.“ Resources, Conservation and Recycling. https://doi.org/10.1016/j.resconrec.2022.106832
Seier, M., et al. 2023. „Prospects for recyclable multilayer packaging: A case study.“ Polymers. https://doi.org/10.3390/polym15132966
Shukla, A., et al. 2022. „Waste pharmaceutical blister packages as a source of secondary aluminum.“ JOM. https://doi.org/10.1007/s11837-021-05038-6
Sufeng, et al. 2017. Plastic-aluminum composite packaging material separating agent based on ionic liquid and separation method thereof.
Tamizhdurai, P., et al. 2024. „A state-of-the-art review of multilayer packaging recycling: Challenges, alternatives, and outlook.“ Journal of Cleaner Production. https://doi.org/10.1016/j.jclepro.2024.141403
USAID/ICMA. 2016. Waste management technologies in regions, Georgia – Quarterly report.
Vagnoni, M., et al. 2023. „Recycling of multilayer packaging waste with switchable anionic surfactants.“ Resources, Conservation and Recycling. https://doi.org/10.1016/j.resconrec.2023.107141
Wong, S. S., et al. 2024. „Solvent-targeted recovery of all major materials in beverage carton packaging waste.“ Resources, Conservation and Recycling. https://doi.org/10.1016/j.resconrec.2023.107367



